Introduction to Electroanalytical Chemistry - MC230P80

• Anglický název: Introduction to Electroanalytical Chemistry
• Český název: Úvod do elektroanalytické chemie
• Zajišťuje: Katedra analytické chemie (31-230)
• Fakulta: Přírodovědecká fakulta
• Platnost: od 2015 do 2015
• Semestr: letní
• E-Kredity: 2
• Způsob provedení zkoušky: letní s.:kombinovaná
• Rozsah, examinace: letní s.:2/0, Zk [HT]
• Počet míst: neomezen
• Minimální obsazenost: neomezen
• 4EU+: ne
• Virtuální mobilita / počet míst pro virtuální mobilitu: ne
• Stav předmětu: vyučován
• Jazyk výuky: angličtina
• Poznámka: povolen pro zápis po webu
• Garant: RNDr. Hana Dejmková, Ph.D.
• Vyučující: RNDr. Hana Dejmková, Ph.D.; RNDr. Jan Fischer, Ph.D.; doc. RNDr. Karolina Schwarzová, Ph.D.; prof. RNDr. Vlastimil Vyskočil, Ph.D.

Anotace

Poslední úprava: doc. RNDr. Karolina Schwarzová, Ph.D. (24.01.2022)

The course aims to provide theoretical insight into basics of electrochemistry and into commonly occurring modern electroanalytic techniques (conductometry, potentiometry, polarographic and voltammetric methods, amperometric and coulombic methods). Their utilization in inorganic and organic analysis will be emphasized. The lecture is taught in English for Erasmus students.

Literatura

Poslední úprava: doc. RNDr. Karel Nesměrák, Ph.D. (22.05.2015)

1) J. Wang, Analytical Electrochemistry, 3rd edition. Wiley, 2006

2) A.J. Bard and L.R. Faulkner, Electrochemical Methods, 2nd Ed., Wiley, 2001

3) R.G. Compton, C.E. Banks, Understanding Voltammetry, 2nd edition, Imperial College Press, 2011.

4) C.M.A. Brett, A.M.Oliveira Brett, Electrochemistry: Principles, methods and applications, Oxford Science Publications, 2000.

Sylabus

Poslední úprava: doc. RNDr. Karolina Schwarzová, Ph.D. (26.02.2019)

1) Review of the basics of electrochemistry (electrical properties, electrode and electrode processes - oxidation, reduction, electrical double layer, electrochemical cell - galvanic and electrolytic cell, electrolysis, two electrode and three electrode setup, indicator, auxiliary and reference electrodes, definition of electroanalytical methods and their classification).

2) Potentiometry (potential, voltage, Nernst equation, standard potential, potential measurements, pH electrodes and pH measurements, ion selective electrodes, potentiometric titrations).

3) Conductometry (electrolytical mobility, individual ionic conductivity, molar conductivity of electrolytes, Kohlrausch law, conductometric titrations).

4) Voltammetric methods (polarography and voltammetry - basic principles, instrumentation and methods. Ilkovic equation, diffusion, kinetic, catalytic and capacity currents, logarithmic analysis. Voltammetry in quiescent solutions - DC voltammetry, pulse techniques, adsorptive stripping techniques. Cyclic voltammetry. reversible and irreversible processes. Indicator electrodes - mercury-based and carbon-based, chemically modified electrodes. Hydrodynamic voltammetry - rotating disc electrode.

5) Amperometric and coulombic methods (principles of amperometry and coulometry, Faraday`s law, controlled potential and constant current coulometry, coulometric titration. Hyphenation of liquid-flow techniques with electrochemical detectors)

18.2.16	Schwarzová	Review of the basics of electrochemistry
25.2.16	Schwarzová	Review of the basics of electrochemistry
3.3.16	Schwarzová	Review of the basics of electrochemistry
10.3.16	Vyskočil	Potentiometry
17.3.16	Fischer	Potentiometry
24.3.16	Vyskočil	Conductometry
31.3.16	Vyskočil	Conductometry
7.4.16	Schwarzová	Voltammetric methods
14.4.16	Schwarzová	Voltammetric methods
21.4.16	Schwarzová	Voltammetric methods
28.4.16	Dejmková	Amperometric and coulombic methods
5.5.16 12.5.16	Dejmková Schwarzová	Amperometric and coulombic methods Review of selected topics