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Course, academic year 2023/2024
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Elementary Processes in Plasma - NEVF502
Title: Elementární procesy v plazmatu
Guaranteed by: Department of Surface and Plasma Science (32-KFPP)
Faculty: Faculty of Mathematics and Physics
Actual: from 2020
Semester: winter
E-Credits: 3
Hours per week, examination: winter s.:2/0, Ex [HT]
Capacity: unlimited
Min. number of students: unlimited
4EU+: no
Virtual mobility / capacity: no
State of the course: taught
Language: Czech, English
Teaching methods: full-time
Teaching methods: full-time
Guarantor: prof. RNDr. Juraj Glosík, DrSc.
Class: DS, fyzika plazmatu a ionizovaných prostředí
Classification: Physics > Surface Physics and P. of Ion.M.
Comes under: Pro rok 2019/2020 + 2021/2022...
Annotation -
Last update: T_KEVF (13.05.2005)
Introduction to physical chemistry (molecular structure, quantum states, ions, etc.), collision processes (ionisation, excitation, quenching, chemical reactions, recombination, etc.). Thermodynamic and statistical thermodynamics in physical chemistry. Reaction kinetics and dynamics. Ion molecule reactions. Introduction to plasma-chemistry.
Course completion requirements - Czech
Last update: doc. RNDr. Jiří Pavlů, Ph.D. (14.06.2019)

Podmínkou zakončení předmětu je úspěšné složení zkoušky.

Literature - Czech
Last update: T_KEVF (13.05.2005)

P.W. Atkins, Physical Chemistry, Oxford University press, 1988.

Yiu Ng, Baer T., Powis I.: Unimolecular and bimolecular ion-molecule reactions, Wiley-Interscience, New York, 1994.

McDaniel E. W., Mitchell J.B. A., Rudd M.E.: Atomic collisions. Heavy Particle Projectiles, Wiley-Interscience, New York 1993.

Requirements to the exam - Czech
Last update: prof. RNDr. Juraj Glosík, DrSc. (10.10.2017)

Zkouška je ústní a požadavky odpovídají sylabu předmětu v rozsahu, který byl prezentován na přednášce.

Syllabus -
Last update: T_KEVF (13.05.2005)
1. Introduction to physical chemistry
Molecular structure, rotational, vibrational and electronic states. Positive and negative ions. Molecular ions, clusters. Hyper surfaces of potential energy. Introduction to spectroscopy. Introduction to quantum mechanical description of collision processes. Franck-Condon principle.

2. Collision processes
Ionisation, penning ionisation, excitation, deexcitation, chemical reaction, ion-molecule reaction, recombination, formation of negative ions, formation of clusters.

3. Thermodynamics and statistical thermodynamics in physical chemistry
Equilibrium and no equilibrium states, thermodynamical equilibrium. Entropy and enthalpy changes in chemical reactions. Equilibrium constant.

4. Reaction kinetics
Rate laws and rate constants. Kinetics of complex reactions. Reaction dynamics. Kinetics of ion-molecule reactions. Electron-ion and ion-ion recombination.

5. Ion-molecule reactions in plasmatic environment
Introduction to plasma and laser chemistries. Relaxation processes in decaying plasma. Reactions in ionosphere and interstellar medium.

6. Experimental techniques
Experimental techniques used in studies of elementary processes.

 
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