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Vibrational Spectroscopy I - MC240P27

Title:	Vibrační spektroskopie I
Czech title:	Vibrační spektroskopie I
Guaranteed by:	Department of Inorganic Chemistry (31-240)
Faculty:	Faculty of Science
Actual:	from 2018 to 2018
Semester:	winter
E-Credits:	3
Examination process:	winter s.:
Hours per week, examination:	winter s.:2/0, Ex [HT]
Capacity:	unlimited
Min. number of students:	unlimited
4EU+:	no
Virtual mobility / capacity:	no
State of the course:	taught
Language:	Czech, English
Additional information:	http://dl2.cuni.cz/course/view.php?id=1239
Note:	enabled for web enrollment

Guarantor:	prof. RNDr. Ivan Němec, Ph.D.
Teacher(s):	prof. RNDr. Ivan Němec, Ph.D.

Opinion survey results Examination dates Schedule

Annotation -

Last update: prof. RNDr. Ivan Němec, Ph.D. (28.02.2018)

This course is a basic course for understanding of the origin, theoretical and practical aspects, analysis and interpretation of infrared and Raman spectra. The course is intended for Master and PhD students.

Literature - Czech

Last update: prof. RNDr. Ivan Němec, Ph.D. (20.09.2021)

Horák M., Papoušek D., Infračervená spektra a struktura molekul, Academia, Praha 1976.

Schrader B., Infrared and Raman Spectroscopy, VCH Publishers, Inc., New York 1995.

Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edition, John Wiley and Sons, Inc., New York 1997.

Milata V., a kol., Aplikovaná molekulová spektroskopia, STU v Bratislavě, Bratislava 2008.

Socrates G., Infrared and Raman Characteristic Group Frequencies, 3rd edition, John Wiley and Sons, Inc., New York 2001.

Requirements to the exam -

Last update: prof. RNDr. Ivan Němec, Ph.D. (22.02.2024)

The examination is oral. The scope of examination agrees with sylabus.

Syllabus -

Last update: prof. RNDr. Ivan Němec, Ph.D. (28.02.2018)

The course is divided into following parts:

1) Energy levels and types of transitions, molecular spectroscopy units, potential energy curves, molecular parameters, selection rules, etc.;

2) Symmetry of molecules, symmetry operations and elements, basic postulates of the group theory, point and space symmetry groups, matrix symmetry presentation, etc.;

3) Infrared and Raman spectroscopy – basic theoretical principles, instrumentation and spectra collection;

4) Vibrational, rotational, vibrational-rotational spectra; rigid rotor, harmonic and anharmonic oscillator, information from vibrational-rotational spectra , etc.;

5) Polyatomic particles vibrations, normal vibrations, number and types of vibrations, symmetry of vibrations, character tables, representations, vibrational spectra interpretations, characteristic group vibrations;

6) Vibrational spectroscopy of inorganic (from 2 to 7 atoms) and coordination compounds (simple ligands, coordination and symmetry); Fermi resonance, tunnel effect, isotopic effect, etc.

7) Vibrational spectroscopy of crystals, vibrational spectroscopy and allotropy and polymorphism studies, etc.