SubjectsSubjects(version: 928)
Course, academic year 2020/2021
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Physical Chemistry - OKB2309012
Title: Fyzikální chemie
Guaranteed by: Katedra chemie a didaktiky chemie (41-KCHDCH)
Faculty: Faculty of Education
Actual: from 2020
Semester: summer
E-Credits: 4
Examination process: summer s.:combined
Hours per week, examination: summer s.:0/0, C+Ex [HS]
Extent per academic year: 10 [hours]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
Virtual mobility / capacity: no
State of the course: not taught
Language: Czech
Teaching methods: combined
Is provided by: OKBE2E106A
Note: course can be enrolled in outside the study plan
enabled for web enrollment
priority enrollment if the course is part of the study plan
Guarantor: doc. Ing. Lidmila Bartovská, CSc.
Is incompatible with: OKBE2E106A
Is pre-requisite for: OKB2309027
Is interchangeable with: OKBE2E106A
Annotation -
Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)
The course is intended for students of chemistry focused on education to yield them a physical point of view on chemical processes. The students will be acquainted with basic laws of thermodynamics and quantities as well as with special fields of physical chemistry ? electrochemistry, chemical kintics, phase and chemical equilibria. The lectures are combined with seminars, where the students are taught to apply the theoretical knowledge to practical problems.
Literature -
Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)

Atkins P.W., de Paula J.: Atkins' Physical Chemistry, Oxford University Press 2006

Requirements to the exam -
Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)

Solving a set of problems assigned by the lecturer

Syllabus -
Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)

1. Basic principles and quantities of physical chemistry. State behaviour of fluids.

2.-5. Chemical thermodynamics. 1st law, internal energy, heat and work, enthalpy. Thermochemistry. 2nd law, entropy, Helmholtz and Gibbs energy. Chemical potential, criteria of equilibrium. 3rd law.

6.-7. Phase equilibria in one-component systems. Phase equilibria in multi-component systems. Vapour-liquid equilibria in ideal and real systems. Solubility of gases in liquids. Colligative properties. Three-component systems, extraction.

8.-9. Chemical equilibria. Criteria of equilibrium, equilibrium constant and its temperature dependence, standard Gibbs reaction energy

10.-11 Chemical kinetics. Rate of reaction, rate constant and its temperature dependence. Reaction order, molecularity. Mechanism of chemical reaction. Kinetic equations of simple and simultaneous homogeneous reactions.

12.-14. Electrochemistry. Equilibria in electrolyte solutions, dissociation of electrolytes, slightly soluble electrolytes. Electrolysis. Conductivity of electrolytes. Galvanic cells.

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