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The course is intended for students of chemistry focused on education to yield them a physical point of view on chemical processes. The students will be acquainted with basic laws of thermodynamics and quantities as well as with special fields of physical chemistry ? electrochemistry, chemical kintics, phase and chemical equilibria. The lectures are combined with seminars, where the students are taught to apply the theoretical knowledge to practical problems.
Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)
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Atkins P.W., de Paula J.: Atkins' Physical Chemistry, Oxford University Press 2006 Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)
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Solving a set of problems assigned by the lecturer Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)
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1. Basic principles and quantities of physical chemistry. State behaviour of fluids. 2.-5. Chemical thermodynamics. 1st law, internal energy, heat and work, enthalpy. Thermochemistry. 2nd law, entropy, Helmholtz and Gibbs energy. Chemical potential, criteria of equilibrium. 3rd law. 6.-7. Phase equilibria in one-component systems. Phase equilibria in multi-component systems. Vapour-liquid equilibria in ideal and real systems. Solubility of gases in liquids. Colligative properties. Three-component systems, extraction. 8.-9. Chemical equilibria. Criteria of equilibrium, equilibrium constant and its temperature dependence, standard Gibbs reaction energy 10.-11 Chemical kinetics. Rate of reaction, rate constant and its temperature dependence. Reaction order, molecularity. Mechanism of chemical reaction. Kinetic equations of simple and simultaneous homogeneous reactions. 12.-14. Electrochemistry. Equilibria in electrolyte solutions, dissociation of electrolytes, slightly soluble electrolytes. Electrolysis. Conductivity of electrolytes. Galvanic cells. Last update: KOTOUCO/PEDF.CUNI.CZ (15.03.2010)
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