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Formal theory of kinetics of phase transformations. Kinetics of chemical reactions, recovery of point defects.
Last update: Šíma Vladimír, prof. RNDr., CSc. (11.05.2007)
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The condition for the completion of the course is passing an oral exam. Last update: Šíma Vladimír, prof. RNDr., CSc. (10.06.2019)
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1. B. Sprušil: Termodynamika pevných látek, skripta UK Praha 1982, II. vydání. 2. P. Haasen: Physical Metallurgy, Cambridge University Press 2nd Edition 1986. 3. M. Hillert: Phase Equilibria, Phase Diagrams and Phase Transformations, Cambridge University Press 1998. 4. D. A. Porter, K. E. Easterling: Phase Transformations in Metals and Alloys, CRC Press, 2nd Edition 2001. 5. W. J. Moore: Fyzikální chemie, SNTL 1981. 6. H. Mehrer: Diffusion in Solids, Springer Series in Solid State Science 155, Springer 2007. Last update: Šíma Vladimír, prof. RNDr., CSc. (18.02.2019)
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lecture Last update: Šíma Vladimír, prof. RNDr., CSc. (10.06.2019)
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The exam is oral one, the extent of the required knowledge corresponds to the syllabus of the lecture in the extent presented at the lecture. Last update: Šíma Vladimír, prof. RNDr., CSc. (10.06.2019)
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1. Kinetics of chemical reactions, equilibrium constant as a function of temperature and composition. 2. Reaction rate, kinetic equations of various orders, balanced, follow-up and side reactions. 3. Point defects. Atomic mechanisms of diffusion. "Up-hill" and "down-hill" diffusion. Diffusion in substitutional alloys. Darken's equations. 4. Solid-solid transformations in metals and alloys, their classification (civilian-diffusional, military-diffusionless). Theory of isothermal transformation kinetics, Avrami equation. Non-isothermal transformations. TTT diagrams, CCT diagrams. Solidification of pure metals and binary alloys.
Last update: Šíma Vladimír, prof. RNDr., CSc. (19.02.2019)
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