Applied Thermodynamics - NBCM231
Title: Aplikovaná termodynamika
Guaranteed by: Department of Macromolecular Physics (32-KMF)
Faculty: Faculty of Mathematics and Physics
Actual: from 2020
Semester: summer
E-Credits: 3
Hours per week, examination: summer s.:2/0, Ex [HT]
Capacity: unlimited
Min. number of students: unlimited
4EU+: no
Virtual mobility / capacity: no
State of the course: taught
Language: Czech, English
Teaching methods: full-time
Teaching methods: full-time
Guarantor: RNDr. Artem Ryabov, Ph.D.
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Annotation -
Last update: Marcela Búryová (14.05.2019)
The lecture course comprises advanced topics of statistical thermodynamics relevant for experimental studies of macromolecular systems.
Course completion requirements -
Last update: RNDr. Artem Ryabov, Ph.D. (14.06.2019)

Oral examination
Literature - Czech
Last update: RNDr. Artem Ryabov, Ph.D. (07.05.2015)

Nejlepší studijní literaturou jsou poznámky z přednášek. Rozšiřující informace lze nalézt v níže uvedených zdrojích.

Knihy:

R. Zwanzig, Nonequilibrium Statistical Mechanics. Oxford University Press, 2001.

D. Chandler, Introduction to Modern Statistical Mechanics. Oxford University Press, 1989.

P. M. Chaikin, T. C. Lubensky, Principles of Condensed Matter Physics. Cambridge University Press, 1995.

И. А. Квасников, Термодинамика и статистическая физика. Том 2, Том 3. УРСС, 2003.

Л. Д. Ландау, Е. М. Лифшиц, Статистическая физика (Том V). Наука, 1964.

I. Prigogine, R. Defay, Chemical Thermodynamics. Longmans Green and Co LTD, 1954.

P. Atkins, J. de Paula, Atkins' Physical Chemistry, 8ed. Oxford University Press, 2006.

Články:

J. Johnson, Thermal Agitation of Electricity in Conductors, Phys. Rev. 32, 97 (1928)

H. Nyquist, Thermal Agitation of Electric Charge in Conductors, Phys. Rev. 32, 110 (1928)

H. B. Callen, T. A. Welton, Irreversibility and Generalized Noise, Phys. Rev 83, 34 (1951)

C. Y. Huang, Determination of Binding Stoichiometry by the Continuous Variation Method: The Job Plot, Methods in Enzymology 87, 509 (1982)

Syllabus -
Last update: RNDr. Artem Ryabov, Ph.D. (14.05.2019)
  • Equilibrium fluctuation theory (probabilistic description, fluctuations in Gibbs canonical ensembles, Einstein’s quasi-thermodynamical fluctuation theory)

  • Thermal noises (Johnson-Nyquist, Langevin), stochastic processes (Gaussian, stationary, correlations, noise spectra), stochastic differential equations, fluctuation-dissipation theorem (Einstein, Callen-Welton)

  • Phenomenological linear non-equilibrium thermodynamics (transport coefficients, Onsager reciprocity relations, generalized susceptibilities), response theory for a two-level atom

  • Introduction to chemical thermodynamics (partial molar quantities, standard enthalpies/entropies, chemical potential), thermodynamic equilibrium of chemical reactions (phase diagrams), equilibrium constant of reaction

  • Rate constants of chemical reaction (transition-state theory, Kramers theory), rate of diffusion-limited reactions (Smoluchowsky model), reactions in gas phase

  • Chemical kinetics

  • Thermodynamics of multi-component and multi-phase systems

  • Colligative properties

  • Thermodynamics of interfaces, nucleation.
Learning resources -
Last update: RNDr. Artem Ryabov, Ph.D. (28.02.2021)

Zoom link:

Topic: Aplikovaná termodynamika (Út 10:40 - 12:10)

https://cesnet.zoom.us/j/96052040260?pwd=anlFZm4yMTZUNUl0MkdzY0NxaU1Ydz09

Meeting ID: 960 5204 0260

Passcode: 412350