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The aim of the subject is to provide basic understanding of scanning probe microscopes and their application in
contemporary basic science. We will learn the basic theories and construction schemes of scanning tunneling microscopes and atomic force microscopes. In addition, we will discuss various measurement principles including advanced spectroscopy (e.g. tunneling, non-elastic tunneling or force spectroscopy). We will learn basic concepts of emerging field of on-surface chemistry as well as recent progresses, which enable to synthetize novel molecular systems which are not available by traditional organic chemistry in solution and gas-phase. For understanding the lectures, basic knowledge of physical, organic and quantum chemistry is assumed. Last update: Zusková Iva, doc. RNDr., CSc. (04.05.2021)
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C. J. Chen Introduction to Scanning Tunneling Microscopy, Oxford University Press, 2008. B. Voigtlander: Scanning Probe Microscopy: Atomic Force Microscopy and Scanning Tunneling Microscopy On-surface Synthesis, Ed. A. Gourdon, Springer 2016 S. Clair, D. de Otyeza, Chem. Rev. 119, 7, 4717-4776 (2019) Last update: Zusková Iva, doc. RNDr., CSc. (04.05.2021)
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The exam has the form of an oral presentation of a topic related to the subject. The presentation is followed by discussion among students. Last update: Zusková Iva, doc. RNDr., CSc. (04.05.2021)
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1. Basics of scanning tunneling microscopy and atomic force microscopy 2. Advanced spectroscopies such as STS, IETS, and sub molecular imaging of organic molecules 3. Relevance of SPM to fields of molecular electronics, 2D materials, spintronics, on-surface chemistry etc. 4. Basic concepts of on-surface chemistry 5. Mechanochemistry 6. Thermally and photoactivated on-surface reactions 7. Supramolecular on-surface self-assemblies 8. On-surface polymerization Last update: Zusková Iva, doc. RNDr., CSc. (04.05.2021)
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