Physical Chemistry II - MC260P02

• Title: Fyzikální chemie II
• Guaranteed by: Department of Physical and Macromolecular Chemistry (31-260)
• Faculty: Faculty of Science
• Actual: from 2013
• Semester: summer
• E-Credits: 4
• Examination process: summer s.:
• Hours per week, examination: summer s.:3/0, Ex [HT]
• Capacity: unlimited
• Min. number of students: unlimited
• 4EU+: no
• Virtual mobility / capacity: no
• State of the course: cancelled
• Language: Czech
• Additional information: http://prfdec.natur.cuni.cz/~pmc/
• Note: enabled for web enrollment
• Guarantor: prof. RNDr. Jiří Vohlídal, CSc.; prof. RNDr. Zdeněk Samec, DrSc.
• Co-requisite : MC260P01
• Pre-requisite : MC260P33, MS710P04A, MS710P04B
• Is pre-requisite for: MC260C11
• Is interchangeable with: MC260P56

Annotation

English

Last update: ZUSKOVA (01.10.2003)

Second part of the basic course on Physical Chemistry, in which classification, terminology, theories and experimental methods of Electrochemistry, Chemical Kinetics, Catalysis and Colloid Chemistry are discussed.

The lecture is copmlemented by C260C02.

Czech

Last update: ZUSKOVA (01.10.2003)

Druhá část základního kurzu fyzikální chemie pro studenty všech chemických oborů, ve které jsou vyloženy klasifikace, terminologie, teorie a experimentální metody elektrochemie, chemické kinetiky, katalýzy a koloidní chemie.

Přednáška je doplněna cvičením C260C02.

Literature

Last update: ZUSKOVA (11.02.2003)

J. Vohlídal, Chemická kinetika, Karolinum, Praha 2001.

Z. Samec, Elektrochemie, Karolinum, Praha 1999.

Requirements to the exam

Last update: prof. RNDr. Jiří Vohlídal, CSc. (18.11.2011)

Zkouška je ústní. Silně akcentováno je skutečné porozumění probrané látce, nikoliv "naučení se" něčeho nazpaměť. Požadováno je též používání správné terminologie a "umění" aplikovat obecné vztahy na řešení příkladů s konkrétními látkami.

Syllabus

Last update: VOHLIDAL (17.12.2002)

Basic terms and definitions, thermodynamic forces, rate of reaction, rate law, classification of reactions from the chemical kinetics point of view, reaction mechanism, steady state approximation, solutions to reaction schemes, chain reactions (linear and branched), experi-mental methods of chemical kinetics (batch and flow reactors), chemical relaxation, theory of elementary reactions (collision theory, transition state theory, calculations of steric factors) reactions in solution, cage effect, diffusion-controlled reactions, reactions controlled by chemical change (influence of the pressure, Coulombic interactions, primary salt effect, sol-vent effects), structure-to-reactivity correlations (Hammett, Taft), principles of catalysis, aci-dobasic catalysis, Hammett's acidity function, enzyme catalysis, adsorption isotherms, hetero-geneous catalysis.

Charge transport in the solid and liquid phases (electronic conductors, electrolytes, conducting polymers, electrodes, galvanic cells, membranes), coulometry, conductometry, electrochemical equilibria, electrochemical potential, theory of activity coefficients of elec-trolytes, dissociation of electrolytes, association of ions, low-soluble electrolytes, protolytic reaktions, inter-phase equilibria, Nernst potential, Donnan potential, electrode potential, elec-trode bilayer, equilibria in galvanic and voltaic cells, electrochemical kinetics, polarization of electrodes, elektrolysers, polarization methods, charge transfer kinetics (reactions involving electrons and ions), transport processes (linear diffusion, spherical diffusion, convective dif-fusion, electroosmotic flow.

Classification and basic properties of dispersion systems - Brownian motion, sedimen-tation, dialysis, electrokinetic phenomena, light scattering, supramolecular membranes.