SubjectsSubjects(version: 901)
Course, academic year 2022/2023
  
Coordination chemistry I - MC240P42
Title: Koordinační chemie I
Czech title: Koordinační chemie I
Guaranteed by: Department of Inorganic Chemistry (31-240)
Faculty: Faculty of Science
Actual: from 2021
Semester: winter
E-Credits: 4
Examination process: winter s.:
Hours per week, examination: winter s.:2/1 Ex [hours/week]
Capacity: unlimited
Min. number of students: unlimited
Virtual mobility / capacity: no
State of the course: taught
Language: Czech, English
Explanation: od 2021 změna rozsahu cvičení na 1h.
Additional information: https://dl2.cuni.cz/course/view.php?id=1245
Note: enabled for web enrollment
Guarantor: prof. RNDr. Petr Hermann, Dr.
Teacher(s): prof. RNDr. Petr Hermann, Dr.
Annotation -
Last update: AGNEMEC (30.04.2002)
The lecture is aimed at the basic priciples of coordination chemistry including the nature of coordination bond and the electronic structure of cations in the ligand field approximation. Introduction to stability constants, stereochemistry and isomerism, substitution and electron transfer reactions, template effect and concept of self-assembly, and overview of various types of coordination compounds and their role in catalysis, molecular electronics and bioanorganic cemistry are another topics of the lecture.
Literature -
Last update: prof. RNDr. Petr Hermann, Dr. (24.09.2020)
  • V. Haber: Koordinační chemie I. SPN Praha, 1990
  • C.E. Housecroft, A.G. Sharpe: Inorganic chemistry (Fourth edition). Pearson, 2012
  • G. Wilkinson: Comprehensive Coordination Chemistry I, Pergamon Press, 1987.
  • N.N. Greenwood, A. Earnshaw: Chemistry of the Elements, Pergamon Press, 1985
  • A.F. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann: Advanced Inorganic Chemistry, Wiley-Interscience, 1999
  • J.R. Gispert: Coordination Chemistry, Wiley-VCH, 2008
  • G.A. Lawrance: Introduction to Coordination Chemistry, Wiley, 2010
Requirements to the exam -
Last update: doc. RNDr. Vojtěch Kubíček, Ph.D. (26.10.2019)

The exam is oral. Required knowledges are given by sylabus.

Syllabus -
Last update: doc. RNDr. Vojtěch Kubíček, Ph.D. (08.10.2013)

  1. Developement of the coordination chemistry.

  2. Electrostatic model and cystal field theory.

  3. Molecular orbitals and ligand field theory. Implications of ligand field splitting: LFSE and lattice and hydratation energies.

  4. Metal–metal bonds and clusters.

  5. Coordination polyhedrons and isomerism, stereochemical non-rigidity (fluxionality), Berry pseudorotation and turnstile rotation. Chirality, absolute configuration and Cotton effect. Jahn-Teller effect.

  6. Stability constants, chelate and macrocyclic effect, Irving-Williams row of stability constant.

  7. Kinetic lability and inertness. Associative, dissociative and interchange mechanism of substitution. Inner sphere and outer- sphere mechanism of electron transfer. Theory of R. Marcus. Oxidative addition and reductive elimination.

  8. Complexes with π-acceptors.

  9. π-complexes, Dewar-Chatt-Dunkinson model.

  10. Template effect and self assembly and preorganisation concept.

  11. Role of coordination compounds in catalysis, molecular electronics and bioanorganic chemistry


 
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