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Course, academic year 2019/2020
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Advances in Analytical Spectrometric Methods - MC230P65
Title in English: Advances in Analytical Spectrometric Methods
Guaranteed by: Department of Analytical Chemistry (31-230)
Faculty: Faculty of Science
Actual: from 2015
Semester: winter
E-Credits: 3
Examination process: winter s.:written
Hours per week, examination: winter s.:2/0 Ex [hours/week]
Capacity: unlimited
Min. number of students: unlimited
State of the course: taught
Language: English
Level: specialized
Guarantor: RNDr. Jakub Hraníček, Ph.D.
Teacher(s): RNDr. Václav Červený, Ph.D.
RNDr. Jakub Hraníček, Ph.D.
RNDr. Jan Kratzer, Ph.D.
RNDr. Mgr. Tomáš Matoušek, Ph.D.
Annotation - Czech
Last update: RNDr. Jakub Hraníček, Ph.D. (03.10.2019)
!!! This course is taught in English for Erasmus students !!!

This course is specialized in the presentation of different topics of modern analytical spectrometry. It covers progress in both molecular and atomic spectrometry. Individual topics are characterized in the syllabus. All lectures are given in English. Attendance at these lectures assumes a basic knowledge of analytical spectrometric methods (subjects MC230P04N or its equivalents and MC230P19). This course is primarily recommended for the pre-gradual, doctoral students and Erasmus students.


Winter semester 2019/2020
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Tuesday, from 8:10 a.m. in the library of the Department of Analytical Chemistry (no. 117)

Speakers:

RNDr. Václav Červený, Ph.D. cerveny2@natur.cuni.cz
RNDr. Jakub Hraníček, Ph.D. hranicek.jakub@natur.cuni.cz
Department of Analytical Chemistry, Faculty of Science, Charles University

RNDr. Jan Srbek, Ph.D. jan.srbek@zentiva.cz
Department of Mass Spectrometry, Zentiva k.s., a Sanofi Company

RNDr. Jan Kratzer, Ph.D. jkratzer@biomed.cas.cz
RNDr., Mgr. Tomáš Matoušek, Ph.D. matousek@biomed.cas.cz
Institute of Analytical Chemistry of the AS CR, v.v.i., Brno
Department of Trace Element Analysis, detached laboratory Prague, Czech Republic


Program:

24.10. Introduction, Information meeting, organization (20 min)

31.10. Miniaturization of Flow Analysis Methods with Spectrometric Detection (Flow Injection Analysis, Sequential Injection Analysis, Bead Injection)

7.11. Sample preparations/analysis without sampling, Excitation Sources / Ionization Sources in Analytical Spectrometry

14.11. Volatile compounds generation (chemical, electrochemical and UV-photochemical way), High-resolution continuous source atomic absorption spectrometry - towards to simultaneous AAS

21.11. Half-day excursion to the Institute of Analytical Chemistry of Academy of Science, Prague
• Advanced approaches to analyte sampling - possibilities and limitations (solids and slurries, electrothermal vaporization, slurry nebulization, generation of volatile compounds)
• Advanced approaches to preconcentration of analytes (especially metals) prior spectrometric detection (cloud point extraction, dispersed liquid-liquid microextraction, magnetic and nanometer-sized materials as sorbents, electrodeposition, solid phase extraction, in-situ trapping of volatile compounds)
• Miniature and low power atmospheric plasmas as sources of ions, atoms and excited atoms
• Element speciation analysis (principles, methods, applications according to elements) and analysis of nanoparticles
• Tour in the IAC laboratories.


28.11. Ion sources - interface technology (electrospray, APCI/APPI), LC-MS spectra demonstration/differences, Mass spectrometer HW introduction (ionization source, ion optics, analyzers, detectors), Mass analyzers/tandem MS (Q, QQQ, Ion Trap, (Q)-TOF, Orbitrap) – applications, differences, pros and cons, Transfer of the Method from HPLC-UV to LC-MS, New ionization techniques DART and MALDI

5.12. Surface Analysis (Static and Dynamic Secondary Ions Mass Spectrometry, Secondary Neutral Mass Spectrometry, Rutherford Backscattering Spectroscopy, Low-Energy Ion Spectrometry, TR and ED X-ray Spectroscopy, Laser Induce Breakdown Spectroscopy

12.12. Written examination



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Winter semester 2020/2021
The subject will be taught in English in similar way as last year. Individual lectures will be specified in the middle of October 2019 according to number of enrolled students.

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Literature - Czech
Last update: RNDr. Jakub Hraníček, Ph.D. (07.08.2019)

Handbook of High-resolution Spectroscopy. Wiley 2011
Laser Chemistry. Spectroscopy, Dynamics and Applications. Wiley 2007
Surface Enhanced Raman Spectroscopy. Analytical, Bioanalytical and Life Science Application. Wiley 2010
Modern Spectroscopy. 4th Ed. Wiley 2004
Vzhledem k aktuálnosti probíraných témat jsou doporučovány též aktuální články z odborných časopisů.

Elektronické materiály jsou dostupné přímo v aplikaci SIS.

Electronic materials are avaible here in SIS application.

Requirements to the exam - Czech
Last update: RNDr. Jakub Hraníček, Ph.D. (30.10.2017)

This subject will be finished by a written exam. The exam will covered all topics lectured during the session.

Syllabus
Last update: RNDr. Jakub Hraníček, Ph.D. (07.08.2019)

1. Highly sensitive modern detectors for UV/VIS spectrum
2. Laser analytical chemistry
3. High-resolution continuous source atomic absorption spectrometry - towards to simultaneous AAS
4. Microwave spectroscopy and remote research of the Universe
5. New types of mass analyzers
6. Advances in optical sensors constructions
7. Using high-frequency electromagnetic fields in medical imaging techniques
8. Spectroscopy of surface enhanced Raman scattering
9. Surface analysis by ion beams
10.New possibilities in X-ray spectrometry
11.Radioanalytical spectral techniques
12.Miniaturization of flow analysis methods with spectrometric detection

 

The lecture is taught in English for Erasmus students.

 
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