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Výsledky projektu Růst isomorfně substituovaných chabazitů pro separaci propylenu/propanu za použití očkování

Výsledky

▼▲Typ výsledku ▼▲Autor celku ▼▲Název celku
(Celkem 7 zázn.)
Yue, Qiudi; Halamek, Jakub; Rainer, Daniel N; Zhang, Jin; Bulánek, Roman; Morris, Russell E; Čejka, Jiří; Opanasenko, Maksym . Tuning the CHA framework composition by isomorphous substitution for CO2/CH4 separation. Chemical Engineering Journal, 2022, sv. 429, s. 131277–131277. ISSN 1385-8947. IF 13.273. [Článek v časopise]
Chemically and structurally flexible zeolites that adapt to coordinate extra-framework cations show a rich variety of gas adsorption behavior. Zeolite framework composition can be tuned to optimize pore geometry and host-guest interaction to improve selectivity. Herein, we report the study on the influence of zeolite framework nature on the separation of CO2/CH4, for CHA system containing variable isomorphously substituted heteroelements (none, B, Al, Ga, and Ti). Their performance has been evaluated by single-component isotherms and the overall separation ability was found to be related to both the geometry of 8-ring pore apertures in CHA and interaction between zeolite host and guest molecules, as revealed by Rietveld refinement of PXRD after dehydration and variable-pressure FTIR spectroscopy. Nearly isotropic geometry of the 8-ring pore opening in Al-CHA (3.84 × 3.89 Å) was obtained, while Ga-CHA exhibits the largest distortion (3.76 × 3.93 Å). Despite the smallest ionic radius of B, both the pore size of 8-ring (3.76 × 3.86 Å) as well as the unit cell volume are the smallest amongst the studied materials. Due to the combination of both the textural and the chemical factors, the maximum CO2 capacity and separation selectivity over CH4 follows the order Al-CHA > Ga-CHA > B-CHA ≈ Si-CHA > Ti-CHA. These observations suggest that tuning the framework composition of zeolite can strongly influence the separation of small molecules such as CO2 and CH4.
Yue, Qiudi; Kutukov, Kristina; Li, Ang; Čejka, Jiří; Zschech, Ehrenfried; Opanasenko, Maksym. Controllable zeolite AST crystallization: between the classical and reversed crystal growth. Chemistry – A European Journal, 2022, sv. x, s. x–x. ISSN 1521-3765. IF 5.236. [Článek v časopise]
DOI: 10.1002/chem.202200590
Zhou, Jingtian; Yue, Qiudi; Opanasenko, Maksym; Chen, Xinyan; Tao, Yajun; Luo, Zhenlin, Revised in the Inorganic Chemistry Frontiers (IF: 6.569) Abstract: The assembly–disassembly–organisation–reassembly (ADOR) approach extends the synthesis of new zeolites. Understanding the disassembly and organisation mechanism is important to optimise the post-treatment process on germanosilicate zeolites. In situ synchrotron X-ray diffraction technique was applied to study the mechanism of these two steps in the HCl vapour that is often unfeasible to capture by conventional ex-situ characterisation. Three germanosilicate zeolites with different pore systems, i.e. UTL, UOV, IWR, were selected as models to compare the reaction behaviours. [Jiný výsledek]
Yue, Qiudi, Results of M-CHA for separation of CO2/CH4 [Jiný výsledek]
Yue, Qiudi, Poster for attending the Workshop on Low dimensional Materials 2020 in Liblice, Czech. [Jiný výsledek]
Yue, Qiudi; Opanasenko, Maksym, This file is the poster for two conferences of Himat 2019 and Workshop on Layered Materials 2019. [Jiný výsledek]
Yue, Qiudi; Opanasenko, Maksym, This attached file is the preliminary results of isomorphously substituted chabazites [Jiný výsledek]