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NMR Spectroscopy of Polymers - NBCM230

Title:	NMR spektroskopie polymerů
Guaranteed by:	Department of Macromolecular Physics (32-KMF)
Faculty:	Faculty of Mathematics and Physics
Actual:	from 2008
Semester:	summer
E-Credits:	3
Hours per week, examination:	summer s.:2/0, Ex [HT]
Capacity:	unlimited
Min. number of students:	unlimited
4EU+:	no
Virtual mobility / capacity:	no
State of the course:	taught
Language:	Czech
Teaching methods:	full-time
Teaching methods:	full-time

Guarantor:	doc. RNDr. Lenka Hanyková, Dr.

Opinion survey results Examination dates SS schedule Noticeboard

Annotation -

Last update: T_KMF (21.05.2007)

Basic course of high-resolution NMR spectroscopy with practical applications in polymer systems.

Aim of the course -

Last update: HANYKOVA/MFF.CUNI.CZ (28.03.2008)

Understanding of basics of NMR spectroscopy. Using of this experimental method for study of polymer systems.

Course completion requirements -

Last update: doc. RNDr. Lenka Hanyková, Dr. (11.06.2019)

Oral exam.

Literature -

Last update: HANYKOVA/MFF.CUNI.CZ (27.03.2008)

H. Günther: NMR Spectroscopy: Basic Principles, Concepts, and Applications in Chemistry

J. K. M. Sanders: Modern NMR Spectroscopy: A Guide for Chemists

P. A. Mirau: A Practical Guide to Understanding the NMR of Polymers

Teaching methods -

Last update: HANYKOVA/MFF.CUNI.CZ (28.03.2008)

Lecture

Requirements to the exam -

Last update: doc. RNDr. Lenka Hanyková, Dr. (10.06.2019)

Oral examination.

Syllabus -

Last update: T_KMF (22.05.2008)

Introduction to NMR spectroscopy. Basic principles and concepts of NMR. Chemical shift. Spin-spin coupling. Relaxation.

NMR experiments. NMR spectrometer. Tuning. Quadrature detection. Acquisition parameters. Pulses. Data processing. Sensivity.

1D and 2D sequencies. Decoupling. Spin-echo. APT. Polarization transfer. INEPT, DEPT. 2D correlation experiments. COSY, TOCSY, HETCOR.

Polymer solutions. Signal assignments. Stereochemistry. Chain tacticity. Branching and endgroups. Copolymers.

Relaxation phenomena. Longitudinal and transverse relaxation. Measurement of relaxation times. Relaxation mechanisms. Dipol-dipol interaction. Correlation function and spectral density. NOE. Correlation time. Chemical exchange. Diffusion coefficient.

Relaxation experiments in polymer systems. Chain mobility in solution. Interactions polymer-solvent, polymer-polymer. Transition coil-globule.

NMR of solid state. Dipole interaction, CSA. Magic angle spinning. Dipolar decoupling. Cross-polarization.

Polymers in solid state. Amorphous and semicrystalline polymers. Polymer blends. Curing. Polymer dynamics in solid state. Spin diffusion.

NMR imaging.