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Ion and Vibrational Spectroscopy - NEVF168

Title:	Iontové a vibrační spektroskopie
Guaranteed by:	Department of Surface and Plasma Science (32-KFPP)
Faculty:	Faculty of Mathematics and Physics
Actual:	from 2020
Semester:	winter
E-Credits:	5
Hours per week, examination:	winter s.:2/1, C+Ex [HT]
Capacity:	unlimited
Min. number of students:	unlimited
4EU+:	no
Virtual mobility / capacity:	no
State of the course:	taught
Language:	Czech, English
Teaching methods:	full-time
Teaching methods:	full-time
Additional information:	https://physics.mff.cuni.cz/kfpp/rozvrh.html

Guarantor:	doc. RNDr. Viktor Johánek, Ph.D. prof. RNDr. Karel Mašek, Ph.D.

Opinion survey results Examination dates WS schedule Noticeboard

Annotation -

Last update: doc. RNDr. Jiří Pavlů, Ph.D. (14.05.2018)

Advanced methods, experimental equipment and other topics related to surface science, thin films, heterogeneous catalysis and chemical physics, extending core lectures of the Surface and Interface Physics study branch. Ion spectroscopies, vibrational spectroscopies, PEEM and LEEM microscopies, operando methods, chemical reactors, gas sensors.

Course completion requirements -

Last update: doc. RNDr. Jiří Pavlů, Ph.D. (14.05.2018)

Examination is oral. Scope of the examination corresponds to the sylabus to the extent presented at the lectures.

Literature -

Last update: doc. RNDr. Jiří Pavlů, Ph.D. (14.05.2018)

Practical Surface Analysis (second edition), Volume 2: Ion and Neutral Spectroscopy, edited by D. Briggs and M.P. Seah, John Wiley and Sons, 1992

E. Bauer, Surface Microscopy with Low Energy Electrons, Springer, 2014

Vibrational Spectroscopy of Molecules on Surfaces, edited by T.E Madey and J.T. Yates Jr., John Wiley and Sons, 1987; Barbara Stuart, Infrared Spectroscopy: Fundamentals and Applications, Wiley and Sons, 2005; Y.J. Chabal, Surface Infrared Spectroscopy, Surf. Sci. Rep. 8 (1988) 211-357

Practical Surface Analysis (second edition), Volume 1: Auger and X-ray Photoelectron Spectroscopy, edited by D. Briggs and M.P. Seah, John Wiley and Sons, 1990; Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, edited by D. Briggs and J.T. Seah, IM Publications 2003

R.J. Stetter, J. Li, Amperometric gas sensors - a review, Chemical Reviews 108 (2008) 352-366; K. Potje-Kamloth, Semiconductor junction gas sensors, Chemical Reviews 108 (2008) 367-399; G. Korotcenkov, The role of morphology and crystallographic structure of metal oxides in response of conductometric-type gas sensors, Materials Science and Engineering R 61 (2008) 1-39

Teaching methods -

Last update: doc. RNDr. Štěpán Roučka, Ph.D. (06.10.2020)

The lecture is conducted on-line in the winter semester 2020. For more information, see https://physics.mff.cuni.cz/kfpp/rozvrh.html

Requirements to the exam - Czech

Last update: doc. RNDr. Jiří Pavlů, Ph.D. (04.06.2020)

Zkouška z tohoto předmětu je ústní. Požadavky zkoušky odpovídají sylabu předmětu v rozsahu, který byl prezentován na přednášce.

Syllabus -

Last update: doc. RNDr. Jiří Pavlů, Ph.D. (14.05.2018)

Ion spectroscopy - classification of methods of ion spectroscopy, interaction of ions with solids, SIMS, LEIS (ISS), RBS, comparison of ion methods with other methods of surface analysis.

Vibrational spectroscopy - basic physical principles, rotational-vibrational Raman and infrared spectroscopy, experimental arrangements and types of samples, interpretation of spectra, time-resolved measurement, examples of experimental results.

PEEM and LEEM microscopy - physical principles, experimental equipment (common and dedicated components), imaging modes, spectral information, other modifications and extensions - FE-LEEM, SPLEEM, XPEEM, UV-PEEM.

Operando methods - surface analysis under real reaction conditions, basic methodology, electron spectroscopies of liquids and high-pressure gases (NAP-XPS/PES), microscopy in liquids and high-pressure gases (Ambient AFM, operando STM).

High-pressure chemical reactors - basic concepts of reactivity measurements in high/ambient-pressure gas phase, types of reactors, gas analysis (mass spectrometry, gas chromatography, ...), interpretation and quantification of experimental results, reaction activity, selectivity and conversion.

Gas sensors - common types of gas sensors, properties of sensors and their characterization, test stations for gas sensors, measurement of sensor characteristics in real conditions, interpretation and quantification of experimental results.